扬州大学试题纸.doc

学院系班级学号姓名
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扬州大学试题纸
(2004—2005学年第一学期)
化学化工学院班(年)级课程有机化学(A)卷
学号姓名
题号
一
二
三
四
五
六
七
八
九
十
总分
得分
一、Multiple Choice ( 共10题, 20分)
1. 1 分(7539)
7539
The correct name of above configuration is :
(A)(1)R, (2)R, (3)S (B)(1)R, (2)S, (3)S
(C)(1)S, (2)S, (3)S (D)(1)R, (2)R, (3)R
3. 1 分(0092)
0092
The IUPAC name is :

(A) (2Z,4E)-4-tert-butyl-2,4-hexadiene (B) (2E,4Z)-3-tert-butyl-2,4-hexadiene
(C) (2Z,4E)-3- tert-butyl-2,4-hexadiene (D) (2E,4Z)-4- tert-butyl-2,4-hexadiene
4. 1 分(9415)
9415
The reagent which mon used to distinguish the structure of alcohol is :
Grinard reagent (B) lindlar catalyst
(C) Sorralet reagent (D) Locas reagent
5. 1 分(0066)
0066
The main product of the reaction of 1-methylcyclohexene with HBr is :

(A) 1-bromo-1-methylcyclohexane (B) cis-1-bromo-2-methylcyclohexane
(C) trans-1-bromo-2-methylcyclohexane (D) 1-bromo-3-methylcyclohexane
6. 1分(8613)
8613
The best reagents for the following reaction is ?

7. 1 分(9322)
9322
Conversion of 2-methyl-1-butanol firstly to tosylate by the reaction with TsCl, then to its bromide by the reaction with NaBr. In two steps, which is correct in the following statements.
Retention of configuration in first step, inversion in second step
Retention of configuration in both first and second steps
Inversion of configuration in first step,Retention in second step
Inversion of configuration in both first and second steps
8. 1 分(0064)
0064
pound with molecular formula C6H12 was reacted firstly with O3, then with Me2S to give CH3CHO and CH3COCH2CH3, The structure of pound is:
9. 1 分(7544)
7544
(A) The pound (B) diastereomer (C) enantiomer (D) cis-trans isomer
10. 1 分(0032)
0032
The geometric configuration of carbon atom in alkane i