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IRA N.LEVINE-Physical Chemistry 6th教材.pdf


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IRA N.LEVINE-Physical Chemistry 6th教材.pdf
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PHYSICAL CHEMISTRY
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PHYSICAL CHEMISTRY
Sixth Edition
Ira N. Levine
Chemistry Department
Brooklyn College
City University of New York
Brooklyn, New York
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PHYSICAL CHEMISTRY, SIXTH EDITION
Published by McGraw-Hill, a business unit of The McGraw-panies, Inc., 1221 Avenue of the
Americas, New York, NY 10020. Copyright © 2009 by The McGraw-panies, Inc. All rights
reserved. Previous editions © 2002, 1995, 1988, 1983, and 1978. No part of this publication may be
reproduced or distributed in any form or by any means, or stored in a database or retrieval system,
without the prior written consent of The McGraw-panies, Inc., including, but not limited to, in
work or other electronic storage or transmission, or broadcast for distance learning.
Some ancillaries, including electronic and ponents, may not be available to customers outside
the United States.
This book is printed on recycled, acid-free paper containing 10% postconsumer waste.
1 2 3 4 5 6 7 8 9 0 QPD/QPD 0 9 8
ISBN 978–0–07–253862–5
MHID 0–07–253862–7
Publisher: Thomas Timp
Senior Sponsoring Editor: Tamara L. Hodge
Director of Development: Kristine Tibbetts
Senior Developmental Editor: Shirley R. Oberbroeckling
Marketing Manager: Todd L. Turner
Project Coordinator: Melissa M. Leick
Senior Production Supervisor: Sherry L. Kane
Senior Designer: David W. Hash
Cover Designer: Ron E. Bissell, Creative Measures Design Inc.
Supplement Producer: Melissa M. Leick
Compositor: ICC Macmillan Inc.
Typeface: 10.5/12 Times
Printer: Quebecor World Dubuque, IA
Library of Congress Cataloging-in-Publication Data
Levine, Ira N.
Physical chemistry / Ira N. Levine. -- 6th ed.
p. cm.
Includes index.
ISBN 978–0–07–253862–5 --- ISBN 0–07–253862–7 (hard copy : alk. paper) 1. Chemistry, Physical
and theoretical. I. Title.
QD453.3.L48 2009
541-- dc22 2008002821

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To the memory of my mother and my father
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Table of Contents
Preface xiv
Chapter 1 THERMODYNAMICS 1
1.1 Physical Chemistry 1
1.2 Thermodynamics 3
1.3 Temperature 6
1.4 The Mole 9
1.5 Ideal Gases 10
1.6 Differential Calculus 17
1.7 Equations of State 22
1.8 Integral Calculus 25
1.9 Study Suggestions 30
1.10 Summary 32
Chapter 2 THE FIRST LAW OF THERMODYNAMICS 37
2.1 Classical Mechanics 37
2.2 P-V Work 42
2.3 Heat 46
2.4 The First Law of Thermodynamics 47
2.5 Enthalpy 52
2.6 Heat Capacities 53
2.7 The Joule and Joule–Thomson Experiments 55
2.8 Perfect Gases and the First Law 58
2.9 Calculation of First-Law Quantities 62
2.10 State Functions and Line Integrals 65
2.11 The Molecular Nature of Internal Energy 67
2.12 Problem Sol 内容来自淘豆网www.taodocs.com转载请标明出处.