MOF膜综述样稿.docx

金属有机骨架（MOFs）膜在气体分离方面研究进展


摘要：在过去几年中，对金属有机骨架（MOFs）和其它晶体配位爱好网络从其很高孔隙率扩展到其它引人注目标性质，比如作为金属中心（有时是配体）之间电子和磁耦合。为了探索和利用这些性质，这些框架必需沉积在固体表面上，如电极，SiO2、Al2O3等[1]。在这一基础上讨论了支撑在多种基底上金属有机骨架薄膜涂层应用和潜力。 因为制造这种多孔涂层需求是相当显著，在过去几年中已经开发了多个用于制备薄多孔MOF膜合成方法。本文将介绍多个关键且常见制备方法。
关键词：金属有机骨架；MOF；纳米；基底；沉积;SAM

Research progress of metal organic frameworks (MOFs) membranes for gas separation

abstract: In the last years, metal-organic frameworks (MOFs) and other crystals with networks of interest from its very high porosity to other interesting properties, such as metal (sometimes ligand) between electronic and magnetic coupling. In order to explore and take advantage of these properties, these frameworks must be deposited on a solid surface, such as electrodes, SiO2, Al2O3, and so on. On the basis of this support is discussed in a variety of substrate coating of metal organic framework and potential. This porous coating needs to be clear, in the past few years has developed several synthetic methods used for preparing thin porous MOF article will focus on a few major and common methods of preparation.
Key words: metal-organic framework;MOFs;Nano;substrate;deposition；SAM
金属有机骨架化合物是一个新奇纳米孔结晶材料，其结构是由金属离子或簇以强配位键形式连接多个多样有机配体组成。改变万千有机配体和无机成份使 MOF能够形成多样性拓扑和满意结构，到现在为止，大家合成出了几千种 MOF 材料