石墨烯与聚合物纳米复合材料.pdf

PROGRESS
IN CHEMISTRY 化学进展
DOI:10. 7536 /PC130923
石墨烯及其聚合物纳米复合材料*
张力1 吴俊涛1** 江雷1,2
(1. 北京航空航天大学化学与环境学院仿生智能界面科学与技术教育部重点实验室北京 100191;2. 中国
科学院化学研究所北京 100190)
摘要石墨烯是一种新型的二维纳米碳材料,具有优异的机械性能、电性能和热性能等,是聚合物纳米复
合材料的理想填料。近年来,石墨烯/聚合物纳米复合材料成为聚合物基纳米复合材料的研究热点。本文对
石墨烯及其聚合物纳米复合材料的研究进展进行了综述。首先概述了石墨烯的不同制备方法及石墨烯的共
价与非共价改性途径。然后重点总结了石墨烯/聚合物纳米复合材料的常用制备方法及其机械性能、导电
性、导热性、耐热性及阻隔性能。最后,对该领域所存在的问题进行了总结,并展望了其发展趋势。
关键词石墨烯聚合物纳米复合材料
中图分类号:O613. 71;TQ127 文献标识码: A 文章编号: 1005-281X(2014)04-0560-12
Graphene and Its Polymer posites*
,
Zhang Li1 Wu Juntao 1** Jiang Lei1 2
(1. Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education,College
of Chemistry and Environment,Beihang University,Beijing 100191,China; 2. Institute of Chemistry,Chinese
Academy of Sciences,Beijing 100190,China)
Abstract Graphene is a new nanomaterial with strict two-dimensional layers structure. With excellent
mechanical, high electrical and thermal properties, graphene is the ideal filler for polymer-based
posites. Graphene /polymer posites greatly draw researchers’attentions in recent years. In this
review ,we presented and discussed the current development of graphene /polymer posites. After
introducing various methods to synthesize graphene,covalent and noncovalent functionalization of graphene are
briefly summarized. Particular emphasis is placed on general methods used to fabricate graphene /polymer
posites and mechanical, electrical, thermal, and gas barrier properties of graphene /polymer
posites. Finally,the challenge of this research area was summarized and its future outlook was
prospected.
Key words graphene;polymer;posite
收稿: 2013 年 9 月,收修改稿: 2013 年 11 月,网络出版: 2014 年 4 月 1 日
* 国家自然科学基金项目(No. 51003004,51373007)、北京市自然科学基金项目(No. 2142019)、国家重点基础研究发展计划(973) 项目( No.
2010CB934700,2012CB933200)及中央高校基本科研业务费专项资金和教育部留学回国人员科研启动基金资助
The work was supported by the National Natural Science Foundation of China (No. 51003004,51373007),the Beijing Natural Scien