含苯氧基、联萘氧基、偶氮苯氧基均三嗪衍生物制备和表征.pdf

福建师范大学硕士学位论文摘要 Abstract Inthispaper,cyanuric chloridewhichs缸uc嘶containing threechlorineatoms was used as themain raw material fortheprovision ofs- thedifferent reactivitiesofthethreechlo血e atomsincyanuric chloride,a seriesofnew were received by the step-wise reactionthrough thecontrolling ofthe of pounds werecharacterizedby Elementalanalysis, IR,1HNMR andotherresearchmethods,also thesolubility,thermalstabilityproperties were can besummarized asfollows. chloride and p-nitrophenol as the raw materials,2,4,6 -3-p—nitrophenoxy-1,3,5-triazine Wasprepared bycontrolling of reactiontemperature in acetone wereused fornitroreduction toobtain2,4,6. 一aminophenoxy-1,3, elemental analysis,1H-NMR,IR,TG characterization theproducts obtained,2,4,6—3-P—nitrophenoxy-1,3,5一tfiazine shows good thermal stability which the position temperature was at430" hydrazine catalystsystem shows agood resultin threekindsofreduction methods. chlorideand1,1’BINOL asthe raw materials,NaOH asbase, cetyltrimethyl ammonium bromide asphasetransfercatalyst,poly 2-chloro-4—1,l’-bi naphthyloxy-1,3,5-triazine wereprepared through structure was characterizedusing uv,IR,1H—NMR,RF, by atomic force microscope(AFM),the surfaceofthepolymer filmWasobserved. was abtainedby the reaction of cyanuric chloride and 4,4’-hydroxyazobenzene using w豳got by the reactionof2-Anilino·4,6一dicholoride·1,3,5一traizine and4,4'-hydroxyazobenzene at40"C inthesolvent ,1HNMR,TG DSC,UV wereusedto characterizethe theopticlresponse property of DIATOB Wasstudiedby UV二Ⅵ thesolubility of thetwo products werestudied,PCCAB won’tdissolve even iIlDMF,but DIATOB can bedissolved inmostkinds ofsolvent. 福建师范大学硕士学位论文 Keywords:Cyanuric chloride,dendrimer,binaphthol,azobenzene,interracial polymeri