Characterization of Pore Structure of Fuel Cell Components :的燃料电池组件的孔结构表征.ppt
DR. AKSHAYA JENA AND DR. KRISHNA GUPTA POROUS MATERIALS, INC., ITHACA, NEW YORK, USA Characterization of Pore Structure of Fuel ponents for Enhancing Performance Outline Introduction Through pore throat diameter, distribution, gas permeability & surface area by: Capillary Flow Porometry Capillary Condensation Flow Porometry Hydrophobic through and blind pore volume & distribution by: Vacuapore Through pore volume, diameter, distribution & liquid permeability by: Liquid Extrusion Porosimetry Summary and Conclusion Introduction Pore structure governs ics of physicochemical processes & Flows of reactants and products in fuel cells. Quantitative measurement of pore structure is essential for Design, development and performance evaluation. Technologies for pore structure measurement are currently being developed to characterize plex pore structure of fuel ponents. We will discuss several innovative techniques essfully developed and applied for evaluation of pore structure of fuel ponents. Through Pore Throat Diameters, Distribution, Gas Permeability and Surface Area Importance of Such Properties Through Pores: Fluid flow Pore Diameters: Capillary forces for liquid movement Throat diameters: Separation of undesirable particles Gas permeability: Overall rate of the processes Through pore surface area: Physicochemical processes Effects of stress, chemical environments & temperature: Influence of operating conditions Suitable Characterization Techniques Advanced Capillary Flow Porometry Capillary Condensation Flow Porometry Through Pore Throat Diameters, Distribution, Gas Permeability and Surface Area Advanced Capillary Flow Porometry For wetting liquid: Wetting Liquids fill pores spontaneously e out spontaneously A pressurized inert gas can displace liquid from pores provided: Work done by Gas = Increase in Interfacial Free Energy Basic Principle Advanced Capillary Flow Porometry Pressure needed to displace liquid from a pore: p = 4 γ cos θ/ D
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